Abstract

A new analytical formula is prepared for the concentration fluctuations, in the long-wavelength limits, S cc(0), for Lennard-Jones fluids based on the WCA theory and RPA approximation. This has made it possible to investigate the dependence of S cc(0) on concentration, pressure and temperature throughout the liquid and vapour phases, as well as across the liquid-vapour coexistence regions of the phase diagram of NeAr mixture.

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