Abstract
In alkylations of tertiary amines with chloroacetic acid in aqueous solutions, an increase in the initial concentrations of reagents to a certain level led to an abrupt increase in the initial rates and conversions attained during the control time. Viscosimetric and refractometric data showed that association with reagents occurred in these systems. The structures of associates that determine the character of the concentration effects of the Menschutkin reaction in water were suggested.
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