Concentration and Influence Factors of Organochlorine Pesticides in Atmospheric Particles in a Coastal Island in Fujian, Southeast China

Qibin Lao,Meixun Zhao,Fajin Chen,Liping Jiao,Xia Sun,Liqi Chen

doi:10.4209/aaqr.2018.04.0126

Abstract

Atmospheric particulate samples collected from Pingtan Island in Fujian province were analyzed for 20 organochlorine pesticides (OCPs) with the aims of elucidating the contamination levels and their influence factors, and providing more comprehensive and fundamental data for the risk assessment of OCPs in this coastal area. The concentration of total OCPs ranged from ND (not detected) to 27.25 pg m–3 (an average of 4.30 ± 4.07 pg m–3) and ND to 13.16 pg m–3 (an average of 3.11 ± 2.54 pg m–3) in 2006 and 2007 respectively, and the level are obviously lower than urban, industrial, suburban, and the similar research areas in the coastal areas of Europe. HCH (Hexachlorocyclohexane) and DDT (Dichlorodiphenyltrichloroethane) were the predominant contaminants, followed by Methoxychlor and Endrin, while the levels of Chlordane, Endosulfan, Aldrin and Dieldrin was relatively lower. Obvious seasonal variations in OCP levels correlate significantly with total particulate levels; higher concentrations of most OCP compounds appeared in winter, whereas lower concentrations appeared in summer. The distribution pattern of the level of most OCP compounds might be directly or indirectly influenced by meteorological conditions, and TOC (total organic carbon) is an important factor influencing the persistence of these OCPs in atmospheric particulates. The source of atmospheric particulates was traced by stable carbon isotopes, which indicate that the increased levels of OCPs in winter and spring influenced by the source of polluted air mass during the “heating season” of Northern China. The cancer risk probability was evaluated based on the residual levels of OCPs, and the results show that dermal contact was the primary pathway affecting human health, and the effect of OCP residuals in atmospheric particulates of the coastal area could not be neglected.

Highlights

Organochlorine pesticides (OCPs) are widely concerned as one class of important persistent organic pollutants+ These authors contributed to this paper.(POPs) due to their salient features of bioaccumulation, ubiquity and persistence
The source of atmospheric particulates was traced by stable carbon isotopes, which indicate that the increased levels of organochlorine pesticides (OCPs) in winter and spring influenced by the source of polluted air mass during the “heating season” of Northern China
The present study provided a 2-year dataset of the level of OCP contamination in atmospheric Particulate matter (PM) at Pingtan Island, China

Summary

Introduction

Organochlorine pesticides (OCPs) are widely concerned as one class of important persistent organic pollutants+ These authors contributed to this paper.(POPs) due to their salient features of bioaccumulation, ubiquity and persistence. As a consequence of their high toxicity to biota and humans, most OCPs were banned in most countries from the 1970s to the 1980s (Willett et al, 1998; Wu et al, 2011; Li et al, 2014; Qu et al, 2015). They could still be found in various environmental media on a global scale (Li et al, 2009; Yu et al, 2013; Gai et al, 2014; Evenset et al, 2016). Particulate matter (PM) in atmosphere is the main pollutant affecting

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