Abstract

The technique of computer simulation is used to compute some molecular dynamical properties of liquid CH2CL2. The results are compared with experimental data from a variety of spectral sources, and emphasize the importance of keeping to an accurate representation of the shape of CH2 CL2 through a five-atom Lennard-Jones potential. The nature of the interaction between a tagged molecule and its thermal bath gives rise to non -gaussian statistics in the interval t = O to a few picoseconds. The same source is responsible for rotation-translation coupling, clearly observable in the moving frame of reference defined by the three principal moment of inertia axes of the asymmetric top CH2CL2

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