Abstract
Reactions involving two [H,C,Si]- anions with the protonated neutral analogues (HSiCH, H2CSi, and H2SiC) have been studied. Calculations through fourth-order perturbation theory (MP4) suggest possible routes for single-proton transfer between the silaacetylide [HCSi]- anion and neutral species. Various important reaction paths for proton-transfer reactions and internal rearrangements of ion−molecule complexes are discussed. Accurate estimates of the acidity of HSiCH and H2SiC are presented and discussed in light of earlier experimental studies.
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