Abstract
Ab initio calculations were carried out to study the inner-valence electron ionizations of C 2H 4, C 2H 2 and H 2S by using SAC and SAC CI methods. We assigned satellite peaks of these molecules and discussed the ionization mechanism. The peak at 19.5 eV of H 2S is interpreted as the 2B 2 satellite peak. We could not find the 2A 1 peak measured by electron momentum spectroscopy in this binding energy region.
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