Computational investigation on the flow and mass transfer properties inside ejector of loop reactor based on CFD-PBM simulation

Abstract

Conventional stirred kettle reactors suffer from inadequate gas-liquid mixing in many production processes, and their reaction rates are greatly limited. The loop reactor can achieve high mass transfer rates with low energy consumption. It is well suited for multiphase reactions with limited mass transfer and has the advantage of being excellent sealing and low cost. In this paper, ejector as the core of the loop reactor was investigated. Combining the Computational Fluid Dynamics (CFD) and Population Balance Model (PBM), the industrial-scale ejector model was constructed. The detailed motion behavior of bubbles and bubble size distribution were predicted. Due to the entrainment of the liquid phase, the gas enters the suction chamber and throat of the ejector, where the gas is mainly sheared and broken, providing a large specific surface area of the gas-liquid interface. Moreover, the flow and transfer properties were closely related to parameters such as nozzle-throat diameter ratio and liquid inlet velocity. Based on the results of the simulation, the gas-liquid mass ratio and the volumetric mass transfer coefficient were correlated with the structure and process parameters, and the correlation model was obtained, which provides guidance for the design of the loop reactor.