Abstract

This paper presents the first implementation of the row-orthonormal hyperspherical coordinate formalism for the computation of the vibrational spectrum of a tetratomic system. The wavefunction of Ne4 is expanded on a large basis set of hyperspherical harmonics generated numerically. This method not only provides spectra with reasonable accuracy, but also gives physical insight into the vibrational dynamics of the system. The characteristics of the spectra are related to the symmetry and localization of the wavefunction in configuration space.

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