Compression of liquid Ni and Co under extreme conditions explored by x-ray absorption spectroscopy

Abstract

The compression of liquid nickel and cobalt has been investigated up to 102 and 83 GPa, respectively, by x-ray absorption spectroscopy at the Ni and Co $K$ edges, using laser-heated diamond anvil cell. A shortening of about 8%--10% of the metal bond distances is observed in the pressure range considered and the experimental results are confirmed by theoretical calculations. Ab initio quantum molecular dynamics calculations have been performed, providing a model pair distribution function for cobalt, used as a starting model in the extended x-ray absorption fine structure analysis. The specific volume of the liquid has also been estimated and compared to calculations in the literature. This work sets the basis for x-ray absorption spectroscopy studies of liquid metals under extreme conditions with potentially important implications for the understanding of Earth and planetary interiors.