Comprehensive life cycle assessment of NH2-functionalized magnetic graphene oxide for mercury removal: Carbon emissions and economic evaluation

Abstract

Heavy metals contamination critically affects human health and ecosystems, necessitating pioneering approaches to diminish their adverse impacts. Hence, this study synthesized aminated magnetic graphene oxide (mGO-NH2) for the removal of mercury (Hg) from aqueous solutions. Although functionalized GO is an emerging technology at the early stages of development, its synthesis and application require special attention to the eco-environmental assessment. Therefore, the life cycle assessment and life cycle cost of mGO-NH2 were investigated from the cradle-to-gate approach for the removal of 1 kg Hg. The adsorption process was optimized based on pH, Hg concentration, adsorbent dose, and contact time at 6.48, 40 mg/l, 150 mg/l, and 35 min, respectively, resulting in an adsorption capacity of 184.17 mg/g. Human carcinogenic toxicity with a 40.42% contribution was the main environmental impact, relating to electricity (35.76%) and ethylenediamine (31.07%) usage. The endpoint method also revealed the pivotal effect of the mGO-NH2 synthesis on human health (90.52%). The most energy demand was supplied by natural gas and crude oil accounting for 70.8% and 22.1%, respectively. A 99.02% CO2 emission originated from fossil fuels consumption based on the greenhouse gas protocol (GGP). The cost of mGO-NH2 was about $143.7/kg with a net present value of $21064.8 per kg Hg removal for a 20-year lifetime. Considering the significant role of material cost (>70%), the utilization of industrial-grade raw materials is recommended to achieve a low-cost adsorbent. This study demonstrated that besides the appropriate performance of mGO-NH2 for Hg removal, it is essential that further studies evaluate eco-friendly approaches to decrease the adverse impacts of this emerging product.