Comprehensive analysis of physical, mechanical, thermal and attenuation characteristics of NaF - B2O3 – Bi2O3 - Sm2O3 glasses for gamma radiation shielding applications

Abstract

A glass system with the nominal composition 10NaF - (89-x)B2O3 - xBi2O3 - 1Sm2O3 (where x = 15, 20, 25, 30, and 35 mol%) has been fabricated by the melt quenching technique. Densities increased from 3.598 to 4.726 g/cm³ and a corresponding rise in molar volume from 35.880 to 44.089 cm³/mol. The decrement in oxygen packing density (OPD = 75.250–61.239 mol/cm3) and increment in oxygen molar volume (13.289–16.329 cm3/mol) indicate an expansion of the glass structure with the Bi3+ ions. Young's modulus decreases from 58.974 to 41.685 GPa as the concentration of Bi2O3 increases from 15 to 35 mol%. The linear attenuation coefficient (LAC) shows an increasing trend, demonstrating improved attenuation ability with a higher molar concentration of Bi₂O₃. As the Bi₂O₃ concentration increases in the glass matrix, the effective atomic number (Zeff) increases from 61.214 to 72.116 at 59.54 keV, and from 15.829 to 25.988 at 662 keV. The half-value layer (HVL) decreases as bismuth oxide is introduced into the glass matrix, and prepared glasses exhibit lower values than Hematite-Serpentine Concrete, Ilmenite-Limonite Concrete, Basalt-Magnetite Concrete, Ilmenite Concrete, RS253, 55B2O3:20BaCO3:19.5ZnO:5Bi2O3:0.5Dy2O3, RS 323, LSGB1, and LSGB2 shielding materials. The mean free path (MFP) values reduced from 0.094 to 0.053 cm at 59.54 keV, and from 2.958 to 2.073 cm at 662 keV with the Bi2O3 concentration. Consequently, the prepared glass can be reliable for gamma radiation shielding applications.