Abstract
Runoff from roads is well recognized as containing a host of heavy metals that may degrade water quality. This awareness has driven a focus towards management strategies intended to attenuate the transport of heavy metals to nearby water bodies. Composted biomass has been shown to have the ability to retain common roadway runoff pollutants, leading to interest in its use as a filter material for the protection of environmentally sensitive areas. Compost biofilters can be constructed in a tubular geometry to intercept surface flow and can be amended with polymers for the targeted removal of specific pollutants. Addressing the need for validation of this concept under field conditions, commercially available tubular biofilters with three different polymeric amendments were studied to assess their efficiency in removing heavy metals and total suspended solids. The filters each contained a mixture of municipal compost and were installed in series as a treatment train adjacent to a busy section of highway 401 in southern Ontario, Canada. Untreated inflow concentrations of chromium, cadmium, copper and lead exceeded Ontario Provincial Water Quality Objectives (PWQO). The biofilter treatment train reduced chromium to below its PWQO, while copper remained above. Results demonstrate removal efficiencies for the treatment train ranging from 15.5% (nickel) to 93.6% (chromium). The low removal efficiency of nickel is attributed in part to its low inflow concentration. Each consecutive filter also reduced TSS concentrations, with an event mean removal efficiency of 50% for the treatment train as a whole.
Highlights
Runoff from roads has been implicated as a significant cause of freshwater impairment (Bartlett, Rochfort, Brown, & Marsalek, 2012; Gazendam, Gharabaghi, McBean, Whiteley, & Kostaschuk, 2009; Trenouth & Gharabaghi, 2016)
A primary objective of this study is to provide insight into the heavy metal removal efficiency of commercial compost biofilters containing an additive for targeted removal of heavy metals
Since Cu remained above its Provincial Water Quality Objectives (PWQO) after exiting the treatment train, the observation that concentrations of Cu were approximately 20 μg/g higher in third biofilter battery is of note
Summary
Runoff from roads has been implicated as a significant cause of freshwater impairment (Bartlett, Rochfort, Brown, & Marsalek, 2012; Gazendam, Gharabaghi, McBean, Whiteley, & Kostaschuk, 2009; Trenouth & Gharabaghi, 2016). Road salt, which is heavily applied to roads in northern climates as a deicing agent, contains trace quantities of heavy metals (Betts, Gharabaghi, & McBean, 2014; Brown & Peake, 2006; Kilgour, Gharabaghi, & Perera, 2014; Perera, Gharabaghi, & Noehammer, 2009). These pollutants accumulate on the road surface and are rapidly washed off during rain and snowmelt events, ending up in nearby soil, sediment, surface water, or groundwater. Highway runoff concentrations of Cu, Zn, and Pb observed in the literature were synthesized by Trenouth and Gharabaghi (2015b), esr.ccsenet.org
Sign-in/Register to view highlights & summary Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
