Abstract

In an effort to reduce raw material cost and improve the charge retention characteristic of nickel metal hydride batteries, the Ti, Zr, and Ni-contents in vanadium-free AB 2 metal hydride alloys were optimized according to their capacity, charge retention, activation, high-rate capability, low-temperature performance, and cycle stability. A multi-component hypo-stoichiometric AB 2 alloy with a composition of Ti 10Zr 27Cr 8Mn 15Co 5Ni 35 was identified and compared to vanadium-containing AB 2 metal hydride alloys. Vanadium-free alloys provided better charge retention performance but with a trade-off in cycle life. The gaseous and electrochemical storage properties were correlated to both the average composition and the stoichiometry of the main AB 2 phases.

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