Composition, variation and contribution of chromophoric dissolved organic matter in Laizhou Bay estuaries, North China

Abstract

To address the complex biogeochemical processes and potential function of dissolved organic matter (DOM) in estuaries before it enters the sea, water samples were collected seasonally in a dozen Laizhou Bay estuaries and in the Yellow River estuary, North China. The results showed that chromophoric dissolved organic matter (CDOM) varied in abundance but had consistent spectral slopes at the same sampling time. Gradually, CDOM decreased while spectral slopes increased from freshwater to seawater. The spectral slope of CDOM varied temporally (higher in October and lower in August) more than it varied spatially. The fluorescent components and biological indices of CDOM indicated that in situ biological activities were the dominant sources in the waters examined in this study. The CDOM was generally more variable than the dissolved organic carbon (DOC) in most of the estuaries. However, marine CDOM may obviously increase in estuaries when indirectly stimulated by rapidly decomposing terrestrial DOM.