Abstract

Tests on pure calcium hydroxide solutions have shown that solubility of calcium hydroxide decreases when alkali content increases. With addition of sulfate Ca 2+, concentration of the solution is higher than without it. Higher Ca 2+ concentration is not due to an oversaturation with Ca(OH) 2 but to the higher solubility of calcium sulfate. A similar result also was attained in solutions which are in contact with cement. In those cases Ca 2+ concentration in the solution decreased to the same extent the originally dissolved sulfate was precipitated as ettringite or monosulfate and finally it reached the value corresponding to the Ca(OH) 2 equilibrium. The solutions' pH value rose with increasing alkali content. This effect, however, clearly decreased from potassium to sodium to lithium. If lithium was added to a solution already containing potassium, the pH value decreased although OH-concentration of the solution continued to increase.

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