Abstract

We study the low-energy vibrational dynamics, called the boson peak (BP), of binary lithium borate glasses as a function of the composition of these glasses by inelastic neutron and Raman scattering. Firstly, we analyze the variations in the properties of the BP with the composition. The position and intensity of the BP linearly change with increasing x owing to the changes in the intermediate glass structures. Secondly, we demonstrate that all spectral shapes with different compositions can be scaled by a single master curve, and are the same for all spectra. The results suggests that there is a universal distribution of the vibrational density of states, which does not change with the composition, even though the structures of lithium borate glasses markedly change. The effect of Li 2 O doping can be understood to be a chemical structure-induced densification.

Highlights

  • Composition Dependence of the Boson Peak and Universality in Lithium Borate Binary Glasses: Inelastic Neutron and Raman Scattering Studies

  • We study the low-energy vibrational dynamics, called the boson peak (BP), of binary lithium borate glasses as a function of the composition of these glasses by inelastic neutron and Raman scattering

  • The results suggests that there is a universal distribution of the vibrational density of states, which does not change with the composition, even though the structures of lithium borate glasses markedly change

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Summary

Journal of the Physical Society of Japan

Composition Dependence of the Boson Peak and Universality in Lithium Borate Binary Glasses: Inelastic Neutron and Raman Scattering Studies. We study the low-energy vibrational dynamics, called the boson peak (BP), of binary lithium borate glasses as a function of the composition of these glasses by inelastic neutron and Raman scattering. We study the BP in binary LiB glasses as a function of x using a combination of inelastic neutron and Raman scattering, and show that the marked variation of the BP induced by changing x can be explained on the basis of a recent finding.12) Another important topic in study of the BP is to investigate the pressure or temperature dependence of the BP. 1(a), the compositional variations of Raman spectra show a similar trend to those of the INS spectra, indicating the consistency of the present experimental results between the

Reduced Raman intensity
Scaled dynamic structure factor
Scaled reduced Raman intensity
Debye level
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