Abstract
1. Using19F,27A1, and1H NMR methods, all the fluoroaluminate complexes of composition [AlFn (H2O)6−n]−n (n=0-6) have been shown to form in aqueous-hydrogen-peroxide solutions, and the F/Al ranges in which they exist have been determined. 2. The fluoroaluminates in the solutions form association complexes that exist as a result of the strong H-bonds between the H2O and F− ligands coordinated in the different complexes. 3. The association of the fluoroaluminates in H2O2 solutions leads to polymerization as a result of the formation of bridging bonds between the fluoroaluminate complexes.
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