Composition and sources of heavy metals in aerosol at a remote site of Southeast Tibetan Plateau, China

Abstract

Knowledge of the elemental composition of aerosols at remote sites is important for evaluating the influence of anthropogenic activities. In this study, the elemental composition and sources of total suspended particles (TSP) at Yaze, a remote site in the southeastern Tibetan Plateau (TP), were investigated. The results showed that the mean elemental concentrations at Yaze were relatively low compared with those in other areas of the TP. Seasonal variations in the studied elements was characterized by low and high concentrations during the monsoon and non-monsoon periods, respectively. The enrichment factors (EFs) for some heavy metals at Yaze were slightly higher than those at Nam Co station (inland TP) but much lower than those at Mt. Yulong (southeastern TP) and in the Indian megacity of Delhi, indicating fewer anthropogenic influences at the study site relative to sites close to severely polluted regions. For the studied elements, three major sources were identified: crustal origins (e.g., Al and Fe), anthropogenic origins (e.g., Zn and Cd) and mixed origins (e.g., As and Bi). Further analysis by potential source contribution functions showed that the local TP was the primary source for elements of crustal origins. Correspondingly, the typical heavy metals were mainly attributed to pollution emitted from anthropogenic activities and transported over long-range from both South and Southeast Asia. This work demonstrates the transport of heavy metals from external sources to remote sites in the southeastern TP. These results are also useful for interpreting the historical profiles of heavy metals in the ice cores of the TP.