Abstract

The oxidative stability of nine hydrocracked base oils from seven producers and a PAO was compared using the standard IP 48 test. After a comprehensive characterisation of the oils, an evaluation of oxidative stability was carried out by measuring some common oil parameters, such as viscosity characteristics, carbon residue, pentane insolubles, and acid number. Additionally, the compound-class composition of the fresh and oxidised oils was determined, and an FTIR spectroscopic analysis was carried out. The oxidative stability of the hydrocracked oils was largely affected by the sulphur and aromatic hydrocarbon concentration in the oils. Oils with an increased sulphur content (above 80 ppm) had better oxidative stability than oils with a low sulphur content (20 ppm and lower), and there was a relatively large variability in the stability of the oils depending on the sulphur concentration. The oxidative stability of most of the hydrocracked oils with a low sulphur content was similar, and matched somewhat the stability of the polyalphaolefin.

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