Abstract
νmax and IÂľmax for the nâĎ* transition of acetone in aqueous solution do not vary monotonically with acetone concentration. The Klotz-Worley R parameter for these solutions shows a maximum at 0.05 x2 whereas carbonyl infrared intensities are a linear function of acetone concentration. Hydrophobic hydration of acetone is proposed in the initial region with direct molecular interaction at approximately 0.20 and 0.45 x2.
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Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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