Complexity of clay mineral formation during 120,000 years of soil development along the Franz Josef chronosequence, New Zealand

Abstract

ABSTRACTWeathering of primary silicates to secondary clay minerals over time affects multiple soil functions such as the accumulation of organic matter and nutrient cations. However, the extent of clay mineral (trans)formation as a function of soil development is poorly understood. In this study, the degree of weathering of sediments along a 120 kyr soil formation gradient was investigated using X‐ray diffraction, Fourier transform infrared spectroscopy and X‐ray fluorescence spectroscopy. Irrespective of site age, mica and chlorite were the dominant clay minerals. During weathering, a remarkable suite of transitional phases such as vermiculite and several interstratifications with vermiculitic, smectitic, chloritic and micaceous layers developed. The degree of weathering was correlated with soil pH and depletion of K, Ca, Na, Fe and Al, regarding both soil depth and site age. Kaolinite occurred especially at the 120 kyr site, indicating slow formation via transitional phases. The findings of this study revealed that long-term soil development caused complex clay mineral assemblages, both temporally and spatially, and linking this variability to soil functioning warrants further research.