Abstract
Abstract The following compounds: TlBr2l. (PyO)2, TlBr2l. (2-PicO)2, TlBr2l. (3-PicO)2, TlBr2l. (4-PicO)2, TlBr2l. (4-Cl-PyO)2, TlBr2l. (4-CN-PyO)2, TlBr2l. (4-NO2-PyO)2 and TlBr2l. (4-CH3O-PyO)2 have been prepared and characterized by elemental analysis. The solids behave as non-electrolytes in acetonitrile solution. The molecular structures of the complexes were studied on the basis of vibrational (IR and Raman) and 1H NMR spectra. The most probable structure is that of a trigonal bipyramid with the halogen atoms in equatorial positions and the two ligands in axial positions.
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