Complexes of Some Pyrido[1,2-a]pyrimidinium Perchlorates with Scandium, Yttrium, and Lanthanum. Crystal and Molecular Structure of 3-Chloro-9-Hydroxy-2,4-Dimethylpyrido[1,2-a]pyrimidinium Perchlorate

Abstract

Complexes of scandium, yttrium, and lanthanum nitrates with 3-chloro-9-hydroxy-2,4-dimethylpyrido[1,2-a]pyrimidinium perchlorate (HL1ClO4) and 9-hydroxy-2,4-dimethylpyrido[1,2-a]pyrimidinium perchlorate (HL2ClO4) were obtained. Their composition was formulated as Sc(LClO4)2(NO3) and M(LClO4)2(NO3)2 (L = L1 or L2; M = Y or La); structures for the complexes obtained were proposed. The crystal and molecular structure of HL1ClO4 was determined. Dissociation and complexation of HL1ClO4 and HL2ClO4 in aqueous ethanol were studied using the spectroscopic method. Ligand dissociation and complexation constants were calculated. It was shown that a chlorine-containing organic ligand only slightly changes the composition and stability of the metal complexes.