Abstract
The values of the paramagnetic shifts and their temperature dependence indicate that the interaction of molecular oxygen with various organic molecules is specific and localized in character; that is it takes place in complexes and not in collision contact pairs. Interactions in collision pairs would not have led to the experimentally observed marked differences in the paramagnetic shifts and their temperature dependence for different fragments of the same molecule, since the orientations of the partners in these pairs are random and almost equally probable.
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