Abstract
Reactions of (2,6-diisopropylphenylimino)acenaphthenone (dpp-mian) with gallium(III), antimony(III), titanium(IV), and cobalt(II) chlorides in toluene lead to the formation of compounds of the formulas [(dpp-mian)2GaCl2][GaCl4], (dpp-mian)SbCl3, (dpp-mian)TiCl4, and [(dpp-mian)CoCl2]2[CoCl2(EtOH)4], respectively. The complexes were characterized by IR and NMR spectra, their structure was established by X-ray crystallography.
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