Abstract
The enthalpies and (in part) free energies and entropies of transfer from pyridine to pyridine + diluent mixtures have been determined for MnCl2py4, Mn(NCS)2py4, Co(NCS)2py4, Ni(NCS)2py4, and NiBr2py4 complexes at 25°C using chloroform or 1,1,2,2-tetrachloroethane (TCE) as diluents. The ΔHtro data indicate specific outer-sphere interactions of the complexes with the diluents. The influence of the kind of anionic ligands and central metal ion of the complexes on their interaction with the diluents are discussed.
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