Abstract
Abstract The first complexes of titanium(IV) with dithiobenzoic acids, specifically [Ti(dtb)3Cl], [Ti(mdtb)3 Cl] (where dtb=dithiobenzoate ion and mdtb=p-methoxydithiobenzoate ion) have been prepared and then hydrolyzed to produce the respective oxo-bridged species, [Ti(dtb)3]2O and [Ti(mdtb)3]2O, which exhibit characteristic strong Ti[sbnd]O[sbnd]Ti absorptions in the IR at 750 and 745 cm−1, respectively. The latter two compounds appear to be the first seven-coordinated oxo-bridged Ti(IV) species involving sulfur-donor ligands. The first tin(IV)-dithiobenzoato complex, [Sn(dtb)2Cl2], was also prepared.
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