Abstract

AbstractA detailed study of poly(alkylthiophene) self-assembly and organization on single-walled carbon nanotubes is presented. We show that ordered polymer domains are formed when a conjugated polymer is blended with small amounts of carbon nanotubes. By correlating the lowest energy feature in the absorption spectra of the polymer with ordering, we demonstrate that the degree of ordering in the polymer is enhanced when it is blended with carbon nanotubes. Furthermore, we elucidated the conformation of the polymer chain when it is absorbed onto the nanotube surface and imaged the high degree of ordering in the polymer/carbon nanotube complex by microscopy.

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