Abstract
Abstract The trianionic binucleating ligands formally derived from the condensation products of S-n-octyldithiocarbazate with either 2-hydroxy- or 2-mercapto-5-methylisophthalaldehyde (hereafter (L″)3- and L3- respectively) gave the binuclear complexes L″Ni2 (CH3 O), L″Ni2 (C6 H5 CH2 O), LNi2 (C3 H3 N2), LCu2 (C3 H3 N2) and LNi2 (SR) where R=C8H1 7 of CH3.C6 H4 and C3 H3 N2 −=the pyrazolate anion. These complexes were soluble in chloroform and 1H n.m.r. data for some of them are presented. There was no evidence for significant magnetic exchange within LCu2 (C3 H3 N2). Attempts to generate LNi2 (X) where X−=Cl−, Br− or I− gave L2 Ni3 in which L3- fails to impose the intended molecular arrangement. Attempts to generate L(Pd(II))2 (X) unexpectedly gave materials containing additional palladium, i.e. LPd4 (CH3 CO2) and LPd4 (C3 H3 N2).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
