Abstract
The photochemical reaction of (CH 3) 4N[B 9H 10CHE] (E = P or As) with group VI metal carbonyls lead to the formation of complexes of the general formula, (CH 3) 4N[B 9H 10CHE M(CO) 5]. Available evidence suggests that the phosphorus or arsenic atom of the ligand is σ-bonded to the metal carbonyl in these new derivatives.
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