Abstract
A large number of derivatives of the diaza-18-crown-6 ligand have been synthesized and characterized. These derivatives have different alkyl or aryl side arms at the nitrogen donor atoms of the macrocyclic diazacrown ether. In some side chains additional donor atoms are available. These diazacrown ethers are used as ligands for the complexation of AgI in MeOH. The complexation reactions have been studied using potentiometric and calorimetric methods. The thermodynamic data show the absence of a lariat effect. The increase of the values of the reaction enthalpies are due only to changes in solvation of the different ligands.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
