Abstract
The compound 1,2-bis(3,5-dichloro-2-hydroxybenzamido)ethane [H4(chba-Et)](1) radily co-ordinates to osmium(VI) as a tetradentate tetra-anion; the X-ray crystal structure of the reduced complex, K2[{Os(η4-chba–Et)(OPPh3)}2–O](3), demonstrates that this ligand can bind as a tetradentate tetra-anion to the equatorial sites of a single octahedral metal centre and the potassium ion is found in two unusual co-ordination environments in complex (3).
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