Abstract
The novel mononuclear Fe(II) complexes of 16-membered P4N2 ligands were synthesized, where octahedral Fe(II) ion is coordinated by four phosphorus atoms of the ligand in equatorial positions and nitrogen atoms of two acetonitrile co-ligands in apical positions. The tetraphosphine ligands demonstrate the RPSPSPRP-configuration regardless of the configuration of the starting stereoisomer of the macrocycles, so that the complexation with iron(II) salts drives up the fixation of this configuration of 1,9-di(R)-1,9-diaza-3,7,11,15-tetraphenyl-3,7,11,15-tetraphosphacyclohexadecanes, which in turn is favorable for the binding of octahedral metal cations.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
