Complexation and Separation of Trivalent Actinides and Lanthanides by a Novel DGA Derived from Macrocyclic Crown Ether: Synthesis, Extraction, and Spectroscopic and Density Functional Theory Studies.

Abstract

A DGA-arm-grafted macrocyclic aza-crown ether ligand (Cr6DGA) was synthesized, and its solvent extraction behavior toward trivalent americium and europium in nitric acid medium was studied. The effects of various parameters such as the contact time, temperature, concentration of the extractant, and acidity on the extraction by Cr6DGA were investigated. It was found that in 3 mol/L HNO3, the SFEu/Am value was about 2. The complexation energies calculated by DFT showed that the Eu(III) complexes were more stable than the corresponding Am(III) complexes in gas, aqueous, and organic phases. Furthermore, the coordination study showed that the metal/ligand ratio of the extracted species was 1:2 by mass spectrometry (MS) analysis. The time-resolved laser-induced fluorescence spectra (TRLFS) further proved that the extracted species contained one water molecule, and so the composition of the extracted complexes may be [EuL2NO3(H2O)]2+ or [EuL2(NO3)2(H2O)]+. Finally, DFT calculations revealed that [EuL2(NO3)2(H2O)]+ is a more stable species and the binding energy of Eu(III) with the DGA unit is lower than that with the crown unit.