Abstract
Rate oscillations during heterogeneous catalytic reactions often display self-similar mixed-mode oscillations that have also been found in various other experimental systems. Spatially nonuniform behavior is revealed by monitoring the surface temperature during complex oscillations in the kinetic regime of the CO oxidation on a Pd supported catalyst at atmospheric pressure. The experimental results demonstrate the influence of global coupling via the gas phase concentration of the deficient component. In addition, the local autonomous frequency appears to be spatially nonuniform. A simple discrete model, a set of globally coupled relaxation oscillators with a frequency distribution, captures qualitatively the experimentally observed behavior.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
