Complex nature of the interaction of AFM tip with the freshly splitted (010) surface of CdWO4 and ZnWO4 single crystals

Abstract

The discovery of new low-dimensional materials formed by splitting known bulk crystals into separate elementary layers has enabled future realization of still undiscovered potential of long-studied materials. High-resistivity two-dimensional films obtained by splitting ionic layered crystals are of great interest for creating new vertical van der Waals heterostructures. For unveiling the potential of using two-dimensional monocrystalline films of CdWO4 and ZnWO4, it is necessary to gain a more penetrating insight into the processes that occur on the freshly splitted surface of the crystals. In the present study, for the first time we investigated the effect of AFM probe on the (010) surfaces of freshly splitted CdWO4 and ZnWO4 single crystals. It is shown that the observed “protruding areas” on the splitted surfaces of these crystals are of a complex nature, and they are mainly related with the transfer of charges, as well as with the formation of complete bonds on the surface of the broken crystal lattice of examined crystals. The charge spots observed on the splitted surface of the crystals arise as a result of local charging by AFM probe. As a result of charge diffusion, as well as under the influence of ambient medium, the complete dissipation of charges occurs in less than 2 h.