Abstract
AbstractPoly(ε‐caprolactone) was found to form inclusion complexes with α‐cyclodextrin to give crystalline compounds. The complexes are stoichiometric one‐to‐one (cyclodextrin: monomer unit) compounds. The yields of the complexes decreased with increasing the molecular weight of the polymer. They were characterized by IR, 1H NMR, 13C CP/MAS NMR, and X‐ray diffraction. The inclusion modes are discussed.
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