Abstract
The complex formation equilibria involving trans-diamminepalladium(II) chloride (PdII), 1,6-hexanediamine (HDA), and DNA constituents were investigated. The formation constant of all possible mononuclear and binuclear complexes were determined at 25 °C and 0.1 mol⋅L−1 NaNO3. The speciation diagrams of the binuclear complex of PdII–HDA–DNA reveal that these complexes predominate in the physiological pH range and the reaction of the binuclear complex PdII–HDA–PdII with DNA constituents is quite feasible.
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