Abstract
Complex formation, and proton transfer processes in the polarizable hydrogen bonds formed, have been studied with 1,8-bis(dimethylaminomethyl)naphthalene N,N′-dioxide (1)+ R-phenol and with 1,2-bis(dimethylaminomethyl)benzene N,N′-dioxide (2)+ R-phenol systems in acetonitrile solutions as a function of the pKa of the substituted phenols. In the first family of systems the complex formation is not complete but increases with decreasing pKa of the phenols, whereas in the second one it is always complete.
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