Abstract
Fe(CO) 5 appeared to be a good catalyst for competitive silylation of olefins (vinylsilanes, styrene) by vinylsilanes and hydrosilane (e.g. Et 3SiH). The catalytic measurements for Fe(CO) 5+ Et 3SiH system and a stoichiometric study on the insertion of olefin into Fe–Si bond in CpFe(CO)SiMe 3 confirm the mechanism of catalysis involving the first reported β-silyl transfer (from carbon of β-silylethyliron) to iron atom accompanied by dehydrogenative silylation of the olefin.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
