Abstract
AbstractThe normal electron‐demand Diels–Alder cycloaddition between cyclopentadiene and methyl vinyl ketone is inhibited by the cycloadduct, when catalyzed by kaolinite‐supported zinc chloride. This inhibition stems from occupation of the catalytic sites by both the cycloadduct and methyl vinyl ketone. Catalysis occurs in this case exclusively by a decrease in the enthalpy of activation.
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