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Abstract
The electrooxidation of pyrrole in electrolytes containing both perchlorate and tetrasulphonato copper (II) phthalocyanine anions produced polypyrrole films from aqueous methanol that were TSCuPc-rich. Potentiostatic and galvanostatic methods gave similar results. However, a similar procedure in acetonitrile produced films that were perchlorate-rich. Electrical conductivity of the films mirrored composition, agreeing with the trend that perchlorate-rich films have higher conductivities than phthalocyanine-rich ones.
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