Abstract

AbstractIn a series of publications we reported on melt rheology, morphology, and mechanical properties of the poly(ethylene terephthalate)/poly(amide‐6,6) blends (PET/PA). The non‐oriented samples had poor interphase bonding resulting in low impact and tensile strengths. To improve these properties the ester‐amide interchange reaction was carried out in solution and in melt. In the latter case a Brabender Plastograph was used in the mixing chamber or twin‐screw extruder configurations with p‐toluenesulfonic acid as a catalyst. The interchange reaction was followed by 400 MHz proton and 13C nuclear magnetic resonance spectroscopy.

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