Comparisons of dielectric and thermodynamic ideality: II. Mixtures of associated liquids

Abstract

Earlier efforts to define ideal composition dependence of the dielectric properties of binary mixtures of Onsager liquids have been extended to the case of mixtures of associated liquids. Two approaches have been adopted. One approach deals solely with bulk properties and closely resembles the treatment of non-structured binary mixtures. The other attempts to incorporate some of the simpler statistical concepts that are embodied in Kirkwood's theory.