Abstract

This study aims to investigate the contamination of Euphrates and Shatt al-Arab with heavy metals. Identifying the pollution degrees and the sources of contamination are among the aims of this study. The fieldwork was carried out in January 2018 by using Stream Sediments Core Sampler Device at depths ranges 20–58 cm from eight river bed sediment sites (from S1 to S12) along the course of Euphrates to Shatt Al-Arab (from north Hilla to Basrah). About twenty-five core samples were chosen for this purpose. Twenty-one of heavy elements were determined by XRF technique. These trace elements are; Ta, W, Ni, Mo, Cr, As, Br, Pb, Co, Ga, Zn, Sr, V, Zr, Mn, Ba, Th, Cu, Rb, Y and Nb. Four indices are selected to evaluate the contamination levels. These are; enrichment factor (EF), the geo-accumulation index (I-geo), contamination factor (CF), and pollution load index (PLI). According to EF mean values, the heavy metals W and Ta recorded a very high enrichment category denoting very high pollution, whilst Ni and Mo referred to a significant category. Nevertheless, the other metals reflected moderate to minimal category. I-geo mean values showed high polluted grade for Ta metal, and moderate polluted grade for Ni, Mo and W metals. However, the other metals were either unpolluted or moderate to unpolluted. Due to CF average values, the heavy elements Ni, Mo, Ta, and W reported very high contamination, but the other elements generally had moderate to low contaminated grade. It was clear that the very polluted heavy elements in the current study were Ta, W, Ni, and Mo. Moreover, the contaminated grade can be ordered as following; Diwania>Simawa>Nasiria>Hilla> Basrah. The high degree of contamination may be mainly attributed to different anthropogenic sources. The other reason maybe originated from the crustal materials of natural origin (lithogenic source).

Highlights

  • In term of hydrography, Euphrates is the longest river in western Asia with a total length of 2940 km, where 40% of its distance (1213 km) lies in Iraq (Al-Bassam and Hassan, 2006)

  • Many sediment pollution indices that can be used to assess the level of contamination by heavy metals, and by taking into account that almost of all sampling sites were located at township areas

  • Enrichment Factor (EF) The Enrichment factor (EF) is considered as an effective tool to evaluate the magnitude of contaminants in the environment (Islam et al, 2015)

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Summary

Introduction

Euphrates is the longest river in western Asia with a total length of 2940 km, where 40% of its distance (1213 km) lies in Iraq (Al-Bassam and Hassan, 2006). Average, and pollution grade of enrichment factor (EF) for heavy metals in the bed sediments of the study area

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