Comparison of traditional and flash pyrolysis of different carbon content silicon oxycarbides

Abstract

This study is to understand the effect of carbon content on the pyrolysis behaviors and phase contents of silicon oxycarbides (SiOCs). Flash pyrolysis conditions, evolution of different SiOC phases, and free carbon types/amounts are compared for C-rich and less C-rich precursors. The C-rich system experiences the flash event at a much lower pyrolysis temperature with a much higher current density even though the internal temperatures at flash are very similar. SiC formation is more obvious for the C-rich samples along with a much higher carbon content under both flash and traditional pyrolysis conditions. The phase contents of SiO2, SiC, and other SiOC intermediates can be calculated using a Gibbs energy minimization method, showing that the C-rich sample has more C-rich SiOC intermediates while the less C-rich sample has more Si-rich intermediates. This research provides a general framework in assessing the pyrolysis behaviors of different SiOC materials.