Abstract
Only H2S consumption and H2O formation was found in the sulfurization of CoMoK/Al2O3 water gas shift catalyst with H2S/H2, but CO2 was formed first, then CH4, H2O and H2S appeared in the later part of TPS with CS2/H2. Carbon deposition on the catalyst during the sulfurization with CS2/H2 caused a lower activity than the catalyst sulfurized with H2S but could be removed in the run of WGS reaction.
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