Abstract
1. There is no full analogy between the gas-chromatographic behavior of thiolic and carboxylic esters. 2. The retention indices of 24 thiolic esters were determined on columns of Apiezon M, silicone OV-17, Triton X-305, and polyethylene glycol 1000 at 130°C. 3. Equations are proposed for the dependence of the retention indices on the number of carbon atoms in the n-alkyl chain on four stationary phases for the homologous series of n-alkyl thioacetates. The equations can be used for the identification of n-alkyl thioacetates in mixtures of sulfur-containing compounds.
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