Abstract

R134a is currently the most widely used refrigerant, whose problem is the high value of the global warming potential, and which will have to be replaced in the near future. Thus far, R1234ze(E) has proven to be the most suitable alternative, but it is slightly flammable. Recently, R1336mzz(E) has emerged as a possible alternative. During the research, the mentioned refrigerants were compared with simulations using the Aspen Plus software package in the case of using groundwater as a heat source. It was found that R1336mzz(E) could be a suitable alternative to R134a since the highest value of coefficient of performance was obtained using it. However, it must be superheated with an internal heat exchanger. The problem with using an internal heat exchanger is that the superheating of the refrigerant vapors affects the isentropic efficiency of the heat pump compressor negatively and, consequently, lowers the COP value of the heat pump. It has been shown that a one percent decrease in isentropic efficiency results in a one percent decrease in the COP value.

Highlights

  • Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, 2000 Maribor, Slovenia; Abstract: R134a is currently the most widely used refrigerant, whose problem is the high value of the global warming potential, and which will have to be replaced in the near future

  • When simulating a heat pump in which heat is transferred by the refrigerant

  • R1336mzz(E) vapors occurs in the heat pump compressor

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Summary

Introduction

Faculty of Chemistry and Chemical Engineering, University of Maribor, Smetanova 17, 2000 Maribor, Slovenia; Abstract: R134a is currently the most widely used refrigerant, whose problem is the high value of the global warming potential, and which will have to be replaced in the near future. It was found that R1336mzz(E) could be a suitable alternative to. R134a since the highest value of coefficient of performance was obtained using it. It must be superheated with an internal heat exchanger. The problem with using an internal heat exchanger is that the superheating of the refrigerant vapors affects the isentropic efficiency of the heat pump compressor negatively and, lowers the COP value of the heat pump. Ergy in the EU is derived from fossil fuels. These are not available in unlimited quantities. In 2018, the strategy was amended to 2030. The complementary strategy 2018/2002 states that the energy effi‐

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