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Abstract
Nuclear resonance studies of the two different types impurity doped potassium hexachloro-stannates, the isomorphic system such as (K-Rb)2SnCl6 and K2(Sn-Re)Cl6 and the nonisomorphic system K2SnCl6:Al3+ in the high temperature cubic phase revealed contrasting features with one the other characterized by static in the former and dynamic feature in the latter case respectively. The resonance spectra of the nonisomorphic system indicate additionally a sign of the local structural transition above the conventional structural phase transition temperature. This seems to be triggered by the ligand-deficient octahedral defects and can be explained in terms of the enhanced activity of the octahedral defects for the hindered rotation.
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